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Keywords: "desktop method" "prediction techniques" "vent sizing" accident accidents accumulation adiabatic ADT ADT24 assessment batch calorimeter calorimetry chemical chemicals chemistry combustion critical decomposition design enthalpy exotherm explosion flammable hazard hazards ignition incident incidents indutrial inherent intrinsic isoperibolic isothermal kinetic kinetics measure measures MTSR network onset prevention rate reaction reactions reactivity reactor risk runaway runaways safety screening Semenov semi-batch stability Stoessel storage synthesis thematic thermal thermodynamic TMR unstable